| ANL | Simba SC | 2-3 ANL |
TP Mazembe |
| 17 | 0 - 1 | Singuluma | |
| 58 | Mkina | 1 - 1 | |
| 64 | 1 - 2 | Kaluyituka | |
| 65 | Samata | 2 - 2 | |
| 72 | 2 - 3 | Kaluyituka | |
| TP Mazembe won 6–3 on agg, but were disqualified for fielding an ineligible player. As a result, Simba will play against Wydad Casablanca, which lost to TP Mazembe in Round 2, in a play-off for a place in the group stage. | |||